Rajiv graduated from St. Stephen's College, Delhi, and thereafter studied at St Edmund Hall, Oxford University Oxford and received his Masters' (MFA) in Film Direction from Columbia University in 1980 .

He started his career in broadcasting on All India Radio on its youth programme at age 12, on television as the anchor of 'Youth Forum' at age 17 in 1970 and as a television journalist with India's National Broadcaster, Doordarshan in 1980s where he also worked as a news anchor. Soon he switched to making television short films and documentaries, and started his in-depth talk show, In Conversation, which got him acclaim. According to TAM (Television Audience Meter) data it has had the highest viewership across all television news channels in India in its genre. The Programme also had the highest viewership across news channels when it was on air on the Doordarshan News Channel on Saturdays at 9.30 pm. It featured people ranging from several Heads of State from George Bush & Vaclav Havel to numerous Nobel Laureates, Baba Amte, Pt. Ravi Shankar, Lord Yehudi Menuhin, and The Dalai Lama, BKS Iyengar to Richard Gere, Zubin Mehta and Mahashweta Devi. It had been through several incarnations over more than twenty years. The programme is currently taking a break.

Rajiv Mehrotra has extensive and pioneering experience in virtually all aspects of television and radio production, as director, cinematographer and editor. He has anchored a range of live and recorded programme genres in English from his early teens. He reported “live” as a news-anchor and served as a reporter for public television during the 1980s on assignments in India and abroad, in particular with Prime Minister Rajiv Gandhi.

From 2000, he has been Managing Trustee, Executive Producer and Commissioning Editor of The Public Service Broadcasting Trust (PSBT) that has produced more than 400 documentary films winning some 85 awards from 250 international film festival screenings. His films have won numerous international and eighteen national awards from the President of India. He has directed films such as a ten part series for television on Sri Ramakrishna (The Great Swan), Angkor Vat (Axis Mundi), the places of Buddhist pilgrimage sites in India (The Footsteps of the Buddha), the ‘Krishnamurthi Schools’ (Awakening of Intelligence), The Tabo Kye monastery (Sacral Legacy), on the Dalai Lama for PBS in the US (Ocean of Wisdom) etc.

Mehrotra manages, as the Honorary Secretary/Trustee, The Foundation for Universal Responsibility of His Holiness The Dalai Lama,, Trustee of the Norbulinka Institute of Tibetan Culture and the Navdanya Trust. He has been a close personal student of His Holiness The Dalai for nearly thirty years.

Mehrotra has twice addressed plenary sessions at ‘The World Economic Forum’ at Davos and was nominated a ‘Global Leader for Tomorrow’ by them. He has served as a Judge for The Templeton Prize for Religion, on the Governing Council of the Sri Aurobindo Society, The Film and Television Institute of India (FTII) and as the Chairman of the Jury of the 50th anniversary Indian National Film Awards for Non-feature films .

Rajiv Mehrotra has been on the Steering Committees of the Planning Commission to recommend policy & strategies for Information & Broadcasting, Information Technology etc, The committee on Bridging The Digital Divide, The Organising Committee of the Mumbai International Film Festival and is a nominated member of the Core Group of the Press Council of India etc.

Mehrotra has published several books including The Mind of The Guru, Understanding The Dalai Lama, The Essential Dalai Lama, "Thakur" a biography of Sri Ramakrishna all by Penguin/ Viking , The Open Frame Reader - on the Indian documentary was published by Rupa. Recently published is a new revised and expanded edition of The Mind of The Guru by Hay House and due early next year, is a book on creativity: The Spirit of The Muse, 2009 also saw the publication of "In My Own Words" by H.H. The Dalai Lama edited by Rajiv Mehrotra and "Conversations with The Dalai Lama on Life, Living & Happiness" both by Hay House, USA. He is working on a spiritual biography of His Holiness The Dalai Lama and a 25 part series for television on Swami Vivekananda.

Mehrotra lives in Delhi with his wife, Meenakshi Gopinath, who is the Principal of the prestigious Lady Shri Ram College for Women, Delhi University.