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Homeschoolestore.com = new freebie every Monday
Handsofachild.com = Quarterly Ebook Freebie, currently deer
Donnayoung.org = tons of free printables, resources
But these aren't things you actually order. Come to think of it, this doesn't answer your question--and I want to know about freebies too! I remember seeing a few things posted on one of my lists--I'll see if I can find them.
You can google "homeschool freebies". There are a couple of sites, which escape me at this time, where there are seveal listing for freebies. I've received everything from coal, a unit study on the USS constitution, food pyramid info, to drug education information.
Instead of doing a 'net search for "homeschooling freebies", do "teacher freebies" or "educator freebies", etc.
The Homeschool Buyers Co-op has lists, too (Free to join there - great deals!)